IIT JEE Physics Practice Paper – Kinetic Theory of Gases (Set 22)
Instructions Total Questions: 20 | Marks: 4 each | No Negative Marking Q1. Kinetic theory explains properties of: Gases Solids Magnets Light Q2. Ideal gas molecules are assumed to have: Negligible volume Large volume Infinite mass No motion Q3. Gas pressure arises due to: Molecular collisions Gravity Magnetism Heat only Q4. RMS speed formula is: √(3RT/M) √(RT/M) 3RT/M None Q5. Average kinetic energy of gas molecule is: (3/2)kT kT 3kT None Q6. Boltzmann constant symbol: k h R G Q7. Degree of freedom means: Independent ways to store energy Molecular force Heat transfer Pressure Q8. Monatomic gas has degrees of freedom: 3 2 5 6 Q9. Equipartition theorem gives energy per degree: (1/2)kT kT 2kT None Q10. Temperature is measure of: Average kinetic energy Pressure Volume Mass Q11. Mean free path is: Average distance between collisions Molecular diameter Gas pressure None Q12. SI unit of temperature: Kelvin Celsius Joule Watt Q13. Internal energy of ideal gas depends on: Temperature Pressure Volume Density Q14. Real gases deviate from ideal behavior due to: Molecular forces No collisions No motion Infinite volume Q15. Pressure of gas increases with: Temperature Decrease in collisions Vacuum None Q16. Most probable speed depends on: Temperature Color Charge Magnetism Q17. Kinetic theory assumes collisions are: Perfectly elastic Inelastic Magnetic None Q18. Gas molecules move in: Random motion Circular paths Straight fixed paths None Q19. Universal gas constant symbol: R k h G Q20. Maxwell distribution describes: Molecular speeds Pressure Heat transfer Electric field Submit Kinetic Theory of Gases – IIT JEE Notes (Set 22) Introduction to Kinetic Theory Definition Kinetic Theory of Gases explains the macroscopic properties of gases in terms of motion of their molecules. Main Idea Gas pressure, temperature, and volume arise due to continuous random motion of molecules. Assumptions of Kinetic Theory Molecular Nature Gas consists of a very large number of tiny molecules moving randomly in all directions. Negligible Volume Actual volume of molecules is negligible compared to volume of gas container. No Intermolecular Forces Except during collisions, no forces act between gas molecules. Elastic Collisions Collisions between molecules and container walls are perfectly elastic. Random Motion Molecules move randomly with different speeds. Gas Pressure Cause of Pressure Pressure of a gas arises due to collisions of molecules with walls of the container. Pressure Formula P = (1/3)ρv²rms Variables ρ = density of gas vrms = root mean square speed Root Mean Square Speed Definition RMS speed is the square root of average of squares of molecular speeds. Formula vrms = √(3RT/M) Key Insight RMS speed increases with temperature. Average Kinetic Energy Formula KE = (3/2)kT Variables k = Boltzmann constant T = absolute temperature Key Insight Average kinetic energy depends only on temperature. Boltzmann Constant Symbol k Value k = 1.38 × 10⁻²³ J/K Importance Connects microscopic molecular energy with temperature. Temperature and Molecular Motion Concept Temperature is a measure of average kinetic energy of gas molecules. Key Insight Higher temperature means faster molecular motion. Degrees of Freedom Definition Independent ways in which a molecule can possess energy. Monatomic Gas Has 3 translational degrees of freedom. Diatomic Gas Has translational and rotational degrees of freedom. Equipartition of Energy Statement Energy is equally distributed among all active degrees of freedom. Energy per Degree Each degree contributes (1/2)kT energy. Total Energy Total energy = (f/2)kT Variables f = degrees of freedom Mean Free Path Definition Average distance traveled by a molecule between two successive collisions. Factors Affecting Mean Free Path Pressure, temperature, and molecular size. Ideal Gas Equation Formula PV = nRT Variables P = pressure V = volume n = number of moles R = gas constant T = absolute temperature Universal Gas Constant Symbol R Value R = 8.314 J mol⁻¹ K⁻¹ Relation Between R and k Formula R = NAk Variables NA = Avogadro number Maxwell Speed Distribution Concept Gas molecules have different speeds distributed statistically. Types of Speeds Most probable speed, average speed, and RMS speed. Relation vrms > vavg > vmp Most Probable Speed Definition Speed possessed by maximum number of molecules. Formula vmp = √(2RT/M) Average Speed Formula vavg = √(8RT/πM) Key Insight Average speed is less than RMS speed. Real Gases Definition Actual gases which deviate from ideal gas behavior. Reason for Deviation Intermolecular forces and finite molecular volume. Boyle’s Law Statement At constant temperature, pressure is inversely proportional to volume. Formula PV = constant Charles Law Statement At constant pressure, volume is directly proportional to temperature. Formula V/T = constant Gay-Lussac Law Statement At constant volume, pressure is directly proportional to temperature. Formula P/T = constant Avogadro’s Law Statement Equal volumes of all gases at same temperature and pressure contain equal number of molecules. Conceptual Insights Key Understanding Kinetic theory connects microscopic molecular motion with observable gas properties. Common Mistakes Students often confuse RMS speed with average speed and misuse temperature units in formulas. Important Exam Concepts Conceptual Traps Average kinetic energy depends only on temperature and not on pressure or volume. JEE Strategy Focus on derivations, gas laws, RMS speed formulas, and molecular motion concepts. Practice numerical problems thoroughly.








