NEET UG – Chemistry Practice Paper (PYQs) – Part 14 | Topic: Hydrocarbons
NEET UG Chemistry Practice Paper – Part 14 (Hydrocarbons) focuses on one of the most fundamental and high-weight chapters of Organic Chemistry. Hydrocarbons form the base of multiple organic reactions and concepts tested in NEET, including alkanes, alkenes, alkynes, aromatic compounds, reaction mechanisms, and orientation effects. Questions from this chapter frequently appear in both direct and application-based formats. This practice paper is designed to strengthen conceptual clarity in substitution, addition, elimination, aromaticity, and reaction conditions. By solving this set, students can reinforce core reaction logic, improve accuracy, and build a strong foundation for advanced organic chemistry chapters. Q1. Which hydrocarbon is saturated? Ethene Ethyne Ethane Benzene Alkanes are saturated hydrocarbons. Q2. General formula of alkenes is: CₙH₂ₙ₊₂ CₙH₂ₙ CₙH₂ₙ₋₂ CₙHₙ Alkenes contain one double bond. Q3. Which hydrocarbon undergoes substitution reaction? Alkane Alkene Alkyne All of these Alkanes mainly undergo substitution. Q4. Markovnikov’s rule applies to: Alkanes Alkenes Alkynes only Aromatic compounds Rule predicts addition in unsymmetrical alkenes. Q5. Which reagent shows anti-Markovnikov addition? HCl HBr + peroxide H₂SO₄ Br₂ Peroxide effect works only with HBr. Q6. Which hydrocarbon is aromatic? Cyclohexane Benzene Hexene Propyne Benzene follows Hückel’s rule. Q7. Hückel’s rule for aromaticity is: 2n π electrons 4n π electrons (4n + 2) π electrons n π electrons Planar cyclic systems with (4n+2) π electrons are aromatic. Q8. Which alkene shows geometrical isomerism? Ethene Propene But-2-ene Methene Restricted rotation around C=C bond. Q9. Ozonolysis of alkene gives: Alcohols Aldehydes/ketones Acids Alkanes Double bond cleavage occurs. Q10. Which reaction converts alkene to alkane? Halogenation Hydrogenation Ozonolysis Hydration Addition of hydrogen in presence of catalyst. Q11. Which alkyne is terminal? But-2-yne Propyne Hex-2-yne Pent-2-yne Terminal alkyne has acidic hydrogen. Q12. Acidity of hydrocarbons follows order: Alkane > Alkene > Alkyne Alkene > Alkyne > Alkane Alkyne > Alkene > Alkane All equal More s-character increases acidity. Q13. Friedel–Crafts reaction occurs in: Alkanes Alkenes Aromatic compounds Alkynes Electrophilic substitution in benzene. Q14. Which catalyst is used in hydrogenation? AlCl₃ Ni Fe CuSO₄ Ni, Pt, or Pd are used. Q15. Which compound decolourises bromine water? Ethane Ethene Benzene Methane Unsaturation causes decolourisation. Q16. Nitration of benzene requires: HNO₃ HNO₃ + H₂SO₄ H₂SO₄ only NO₂ Mixed acid generates NO₂⁺ electrophile. Q17. Which reaction is free radical substitution? Nitration Chlorination of methane Hydrogenation Hydration Occurs under UV light. Q18. Which alkane gives maximum number of monochloro products? Methane Ethane Isobutane Neopentane Different types of hydrogens present. Q19. Which test confirms unsaturation? Lucas test Baeyer test Tollens test Fehling test KMnO₄ test for C=C bond. Q20. Which compound undergoes electrophilic substitution most easily? Ethane Ethene Benzene Ethyne Aromatic stability retained. Q21. Which hydrocarbon gives acetylene on heating? Ethane Methane Calcium carbide Propane CaC₂ + H₂O → C₂H₂. Q22. Which hydrocarbon has maximum heat of combustion? Alkane Alkene Alkyne Aromatic Least stable → highest heat of combustion. Q23. Which compound shows ortho-para directing effect? Nitrobenzene Chlorobenzene Benzoic acid Benzaldehyde Halogens are o-p directing but deactivating. Q24. Which hydrocarbon does NOT give addition reaction? Ethene Ethyne Benzene Propene Aromatic stability prevents addition. Q25. Which reagent converts alkyne to trans-alkene? Lindlar catalyst Na/NH₃ H₂/Pd KMnO₄ Dissolving metal reduction gives trans-alkene. Q26. Which hydrocarbon is used as anaesthetic? Ethane Ethene Cyclopropane Benzene Cyclopropane was used earlier. Q27. Which hydrocarbon undergoes polymerisation? Methane Ethene Ethane Benzene Ethene forms polythene. Q28. Which hydrocarbon is most reactive? Alkane Alkene Alkyne Aromatic Highest unsaturation. Q29. Which hydrocarbon gives soot on burning? Alkane Alkene Aromatic All High C:H ratio gives sooty flame. Q30. Hydrocarbons are important because they: Are fuels Are raw materials Explain organic reactions All of these Hydrocarbons form the base of organic chemistry. Submit Paper Conclusion: Why Part 14 (Hydrocarbons) Is Crucial for NEET Organic Chemistry Success The Hydrocarbons chapter is one of the most important pillars of Organic Chemistry in the NEET syllabus. It introduces students to the behavior of alkanes, alkenes, alkynes, and aromatic compounds—molecules that form the structural backbone of almost all organic reactions. NEET UG Chemistry Practice Paper – Part 14 is designed to ensure that students do not merely memorize reactions, but understand the underlying principles that govern them. One of the primary strengths of this practice paper is its emphasis on reaction types and mechanisms. Hydrocarbons undergo substitution, addition, elimination, oxidation, and polymerization reactions. NEET often tests whether students can correctly identify which reaction type applies under specific conditions. For example, distinguishing between free radical substitution in alkanes and electrophilic addition in alkenes is fundamental. This paper reinforces such distinctions, helping students develop confidence in reaction prediction. The inclusion of questions on Markovnikov and anti-Markovnikov addition ensures that students clearly understand regioselectivity in addition reactions. Many NEET questions are framed around subtle variations in reaction conditions—such as the presence of peroxide in HBr addition—and students who are not conceptually clear often make mistakes. Regular practice through Part 14 eliminates such confusion. A significant component of this chapter is aromatic hydrocarbons and electrophilic substitution reactions. Benzene and its derivatives are repeatedly tested in NEET. Understanding Hückel’s rule, aromatic stability, nitration, halogenation, Friedel–Crafts alkylation and acylation, and directing effects is essential. This paper strengthens students’ ability to predict substitution positions (ortho, meta, para) based on activating and deactivating groups—an area where many aspirants lose easy marks. Another key advantage of practicing this set is the reinforcement of concepts like stability and heat of combustion. Comparing alkane, alkene, and alkyne stability or understanding why aromatic compounds resist addition reactions builds deeper conceptual clarity. NEET often tests these comparative properties rather than straightforward reaction recall. Part 14 also enhances understanding of geometrical isomerism and structural isomerism, especially in alkenes and alkynes. Such questions may appear simple but require careful observation and logical thinking. Practicing them builds accuracy and reduces careless mistakes. The paper further strengthens practical application concepts such as Baeyer’s test for unsaturation, ozonolysis reactions, catalytic hydrogenation, and polymerisation. These reactions are frequently asked either directly or in combination with multi-step reasoning questions. By practicing such MCQs, students become more comfortable analyzing reaction outcomes under different reagents and








