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“Haloalkanes & Haloarenes” NEET UG Practice Paper Chemistry (PYQs) Part 15

NEET UG – Haloalkanes & Haloarenes Chemistry Practice Paper 15 (PYQs)

NEET UG Chemistry Practice Paper – Part 15 (Haloalkanes & Haloarenes) is designed to strengthen students’ understanding of substitution and elimination mechanisms. This chapter is highly important for NEET due to its focus on SN1, SN2, E1, E2 reactions, reactivity trends, and name reactions, all of which are frequently tested.

Total Questions: 30 | Total Marks: 120

Q1. Reactivity of alkyl halides towards SN1 follows:




Tertiary carbocations are most stable.

Q2. Which halogen is best leaving group?




I⁻ is weakest base and best leaving group.

Q3. Which solvent favours SN1 reaction?




Polar protic solvents stabilise carbocation.

Q4. Which reaction follows SN2 mechanism?




Less steric hindrance favours SN2.

Q5. Which compound undergoes nucleophilic substitution most easily?




C–I bond is weakest.

Q6. Aryl halides are less reactive because:




Partial double bond character.

Q7. Wurtz reaction gives:




Coupling reaction using Na in dry ether.

Q8. Which reaction forms alcohol from alkyl halide?




Nucleophilic substitution.

Q9. Which alkyl halide gives maximum elimination?




Tertiary favours E1/E2.

Q10. Which compound reacts fastest with alcoholic KOH?




Tertiary favours elimination.

Q11. Sandmeyer reaction converts:




Cu salts replace diazonium group.

Q12. Finkelstein reaction is used to prepare:




NaI in acetone.

Q13. Which halide gives positive carbylamine test?




Primary amines give foul smell.

Q14. Which compound is most reactive in nucleophilic substitution?




Resonance stabilises intermediate.

Q15. Which compound forms Grignard reagent?




RMgX formed from alkyl halides.

Q16. Which compound undergoes hydrolysis fastest?




Tertiary carbocation stable.

Q17. Which halogen has strongest C–X bond?




C–F bond is strongest.

Q18. Which reagent is used to prepare alkyl fluoride?




Swarts reaction.

Q19. Which alkyl halide undergoes SN2 fastest?




Less steric hindrance.

Q20. Which compound does NOT undergo SN1?




Primary carbocation unstable.

Q21. Which compound undergoes E2 reaction?




Strong base favours E2.

Q22. Which reaction forms alkene from alkyl halide?




Alcoholic KOH.

Q23. Which is most reactive towards nucleophile?




Resonance stabilises carbocation.

Q24. Which reagent gives elimination predominately?




Alcoholic medium favours elimination.

Q25. Which reaction gives coupling product?




Two alkyl groups couple.

Q26. Which halide reacts fastest with NaI in acetone?




SN2 favoured.

Q27. Which compound undergoes nucleophilic aromatic substitution?




−NO₂ activates ring.

Q28. Which halide forms alcohol via SN1?




Stable carbocation formed.

Q29. Which is least reactive?




Resonance stabilised C–Cl bond.

Q30. Haloalkanes are important because they:




They are versatile intermediates.

Conclusion: Why Part 15 (Haloalkanes & Haloarenes) Is Critical for Scoring in NEET Organic Chemistry

The chapter Haloalkanes & Haloarenes is one of the most strategically important sections of Organic Chemistry for NEET aspirants. It connects foundational concepts from General Organic Chemistry with real reaction mechanisms, making it a bridge between theory and application. NEET UG Chemistry Practice Paper – Part 15 is carefully designed to strengthen this bridge and transform a potentially confusing chapter into a high-scoring opportunity.

One of the biggest reasons this chapter matters is its heavy focus on reaction mechanisms. NEET frequently tests SN1, SN2, E1, and E2 mechanisms directly or indirectly. Students often struggle to differentiate when substitution will dominate and when elimination will occur. Through systematic practice in Part 15, learners clearly understand how substrate structure, solvent type, nucleophile strength, and leaving group ability influence the reaction pathway. This clarity dramatically improves accuracy in mechanism-based questions.

Another key area covered in this paper is the stability of intermediates, especially carbocations. Since SN1 reactions depend on carbocation stability, questions often revolve around comparing tertiary, secondary, primary, allylic, and benzylic systems. Practicing such MCQs strengthens students’ ability to predict reactivity trends logically rather than guessing. This analytical approach is crucial for NEET, where subtle conceptual differences determine the correct option.

The paper also reinforces understanding of leaving group ability and bond strength trends. Many students memorize that I⁻ is a better leaving group than Cl⁻ but fail to connect it to bond dissociation energy and stability of the leaving species. By solving structured questions in this practice set, students internalize these trends in a meaningful way, which helps them tackle unfamiliar variations in the exam.

A particularly important section of this chapter involves aryl halides and their reduced reactivity. NEET frequently tests why chlorobenzene is less reactive toward nucleophilic substitution due to resonance stabilization and partial double bond character. Without conceptual clarity, students often confuse haloalkanes with haloarenes. Part 15 ensures that this distinction becomes crystal clear.

The inclusion of name reactions such as Wurtz reaction, Finkelstein reaction, Swarts reaction, and Sandmeyer reaction further strengthens exam readiness. These reactions are commonly asked either directly or as part of multi-step conversion problems. Practicing them in MCQ format improves recall speed and reaction identification skills.

Another major benefit of solving this practice paper is improved understanding of Grignard reagent formation and reactivity, one of the most important synthetic tools in Organic Chemistry. Even if detailed Grignard reactions appear later in the syllabus, mastering their origin in haloalkanes provides a solid conceptual base.

Part 15 also sharpens understanding of elimination versus substitution conditions. Distinguishing between aqueous KOH (substitution) and alcoholic KOH (elimination) is a classic NEET testing area. Small details like solvent medium often determine the correct answer. Practicing such questions trains students to pay attention to these crucial exam cues.

The structured format of 30 MCQs also enhances time management and exam discipline. Students learn to quickly analyze reaction conditions, identify mechanism clues, and select answers confidently without overthinking. This speed-accuracy balance is essential for high performance in NEET.

Equally valuable is the instant explanation-based feedback, which converts every mistake into a learning opportunity. Organic Chemistry errors often stem from conceptual gaps that carry forward into multiple chapters. By correcting misunderstandings early—especially in mechanisms—students prevent future confusion in alcohols, carbonyl compounds, and amines.

In conclusion, NEET UG Chemistry Practice Paper – Part 15 is not just practice—it is mechanism mastery. It strengthens understanding of substitution and elimination reactions, clarifies reactivity trends, builds confidence in name reactions, and sharpens logical reasoning. For NEET aspirants aiming to score high in Organic Chemistry, mastering Haloalkanes & Haloarenes through structured practice is a decisive step toward achieving a strong and reliable exam performance.

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